Pure Ni-Based and Trimetallic Ni-Co-Fe Catalysts for the Dry Reforming of Methane: Effect of K Promoter and the Calcination Temperature
نویسندگان
چکیده
This work investigates the effect of Potassium promoter and calcination temperature on catalytic activity in dry reforming methane reaction compares performance Ni, Co, Fe–Al2O3 trimetallic catalysts with reference Ni–Al2O3. Although higher was achieved Ni–Al2O3, resulted a more favorable CO/H2 ratio considerably better coke resistance. Higher led to increase formation which caused sintering catalysts. Promoting samples 0.5%K order improve resistance, reduced activity.
منابع مشابه
An Investigation into the Effect of Hydrotalcite Calcination Temperature on the Catalytic Performance of Mesoporous Ni-MgO-Al2O3 Catalyst in the Combined Steam and Dry Reforming of Methane
Several mesoporous nickel-based catalysts with MgO-Al2O3 as the catalyst support were prepared using a co-precipitation method at a constant pH. The supports were prepared from the decomposition of an Mg-Al hydrotalcite-like structure which had already been prepared with Mg/Al=1. Prior to impregnating 10 wt.% nickel on the supports, the precursor was decomposed at several ...
متن کاملStructured Ni catalysts on porous anodic alumina membranes for methane dry reforming: NiAl2O4 formation and characterization.
This communication presents the successful design of a structured catalyst based on porous anodic alumina membranes for methane dry reforming. The catalyst with a strong Ni-NiAl2O4 interaction shows both excellent activity and stability.
متن کاملKinetic comparison of Ni/Al2O3 and Ni/MgO-Al2O3 nano structure catalysts in CO2 reforming of methane
The kinetic characteristics of the Ni/Al2O3 and Ni/MgO-Al2O3 catalysts were investigated in CO2 reforming of methane (CRM). The reaction orders (α and β) and the rate constant (k) were calculated using the non-linear regression analysis, in which the sum of the squared differences of calculated and experimental CO2 reforming of m...
متن کاملInvestigation of the catalytic performance and coke formation of nanocrystalline Ni/SrO-Al2O3 catalyst in dry reforming of methane
In this study, nickel catalysts supported on mesoporous nanocrystalline gamma alumina promoted by various strontium contents were prepared by the impregnation method and employed in dry reforming of methane (DRM). The prepared catalysts were characterized using N2 adsorption (BET), temperature-programmed reduction and oxidation (TPR,) and oxidation (TPDTPO), X-ray diffraction (XRD), and scannin...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Catalysis Letters
سال: 2022
ISSN: ['1572-879X', '1011-372X']
DOI: https://doi.org/10.1007/s10562-022-04203-z